Total distance covered: 3558.5 km
| Standing | Rider | Rider number bib | Team | Time | Gaps |
|---|---|---|---|---|---|
| 1. |  SASTRE Carlos | 11 | TEAM CSC SAXO BANK | 87h 52' 52" | |
| 2. |  EVANS Cadel | 1 | SILENCE - LOTTO | 87h 53' 50" | + 00' 58" |
| 3. |  KOHL Bernhard | 115 | GEROLSTEINER | 87h 54' 05" | + 01' 13" |
| 4. |  MENCHOV Denis | 131 | RABOBANK | 87h 55' 02" | + 02' 10" |
| 5. |  VANDEVELDE Christian | 191 | GARMIN CHIPOTLE | 87h 55' 57" | + 03' 05" |
| 6. |  SCHLECK Frank | 17 | TEAM CSC SAXO BANK | 87h 57' 20" | + 04' 28" |
| 7. | SANCHEZ Samuel | 27 | EUSKALTEL - EUSKADI | 87h 59' 17" | + 06' 25" |
| 8. | KIRCHEN Kim | 41 | TEAM COLUMBIA | 87h 59' 47" | + 06' 55" |
| 9. | VALVERDE Alejandro | 31 | CAISSE D’EPARGNE | 88h 00' 04" | + 07' 12" |
| 10. |  VALJAVEC Tadej | 109 | AG2R-LA MONDIALE | 88h 01' 57" | + 09' 05" |
| 11. | EFIMKIN Vladimir | 104 | AG2R-LA MONDIALE | 88h 02' 47" | + 09' 55" |
| 12. | SCHLECK Andy | 16 | TEAM CSC SAXO BANK | 88h 04' 24" | + 11' 32" |
| 13. |  KREUZIGER Roman | 65 | LIQUIGAS | 88h 05' 51" | + 12' 59" |
| 14. |  CASAR Sandy | 161 | FRANCAISE DES JEUX | 88h 12' 15" | + 19' 23" |
| 15. | MOINARD Amaël | 187 | COFIDIS CREDIT PAR TELEPHONE | 88h 16' 23" | + 23' 31" |
| 16. | ASTARLOZA Mikel | 22 | EUSKALTEL - EUSKADI | 88h 16' 32" | + 23' 40" |
| 17. |  SIUTSOU Konstantsin | 49 | TEAM COLUMBIA | 88h 17' 47" | + 24' 55" |
| 18. | BOTCHAROV Alexandre | 83 | CREDIT AGRICOLE | 88h 20' 03" | + 27' 11" |
| 19. |  FOFONOV Dmitriy | 85 | CREDIT AGRICOLE | 88h 21' 23" | + 28' 31" |
| 20. |  NIBALI Vincenzo | 67 | LIQUIGAS | 88h 21' 25" | + 28' 33" |
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